%0 Journal Article %T Efficient Solvent Free Synthesis of 12-Aryl-8,9,10,12-tetrahydrobenzo[a]-xanthen-11-ones and 3H-Spiro[isobenzofuran-1,9'-xanthen]-3-one Derivatives Using Cobalt Hydrogensulfate as a Green, Heterogeneous and Reusable Catalyst %J Organic Chemistry Research %I Iranian Chemical Society %Z 2383-242X %A Eshghi, Hossein %A Eftekhar, M %A Rahimizadeh, M %A Hassanpour, M %A Bakavoli, M %D 2016 %\ 03/01/2016 %V 2 %N 1 %P 20-27 %! Efficient Solvent Free Synthesis of 12-Aryl-8,9,10,12-tetrahydrobenzo[a]-xanthen-11-ones and 3H-Spiro[isobenzofuran-1,9'-xanthen]-3-one Derivatives Using Cobalt Hydrogensulfate as a Green, Heterogeneous and Reusable Catalyst %K Cobalt hydrogensulfate %K Heterogeneous and reusable catalyst %K Xanthene derivatives %K Solvent free %R 10.22036/org.chem..2016.13465 %X      Cobalt hydrogensulfate is an efficient catalyst for the condensation of β-naphthol, aromatic aldehydes and 5,5-dimethyl-1,3-cyclohexanedione at 120 °C to afford 9,9-dimethyl-12-phenyl-8,10,11,12-tetrahydro-9-H-benzo[a]xanthen-11-one derivatives in high yields. Also, polycondensation reactions of phenols with phthalic anhydride were carried out in the presence of cobalt hydrogensulphate under solvent-free conditions. Simple and convenient procedure, high conversion, reusability of catalyst, easy purification and short reaction time are the advantageous features of this method. %U https://www.orgchemres.org/article_13465_00a77f622df9074cb775c35f3f36f804.pdf